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The honeymoon is over for T.I. and his wife Tameka Cottle because TMZ has learned they were arrested tonight and booked for the alleged possession of a controlled substance.

Law enforcement sources tell us L.A. County Sheriff‘s deputies pulled over the multi-platinum selling rapper and his wife in a Maybach on Sunset Boulevard around 10:30PM. Deputies say they smelled marijuana, and after searching the vehicle they arrested T.I. and Tameka.

The couple just got married on July 30 in Miami, and T.I. — real name Clifford Harris Jr. — is on probation after doing seven months in prison on federal weapons charges. Tameka Cottle is a former member of the female R&B group Xscape.

We’re told T.I. and Tameka are in custody right now. Bail amount is $10,000.

Updated- September 3rd

Sheriff’s Department spokesperson Nicole Nishida confirmed that police found a controlled substance in the vehicle described as an unspecified amount of pills that “resembled ecstasy.” Police are currently testing the pills and Nishida said she could not confirm where the pills were found. She also confirmed that there were other passengers in the car who were not charged with any crimes. So far the police have made no mention of possible codeine syrup at the scene.